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Why is zinc blende more stable than wurtzite?

Why is zinc blende more stable than wurtzite?

Summary – Zinc Blende vs Wurtzite Since zinc blend is more thermodynamically stable than wurtzite, the wurtzite form tends to convert into zinc blend slowly. The key difference between zinc blende and wurtzite is that zinc blend is cubic, whereas wurtzite has a hexagonal structure.

Why do zinc blende and wurtzite have different structures when both are ZnS?

The coordination number, the number of of electron pairs donated to a metal by its ligands, for both zinc an sulfur is four. The difference between wurtzite and zincblende lies in the different arrangements of layers of ions.

What is the geometry of ZnS crystal?

ZnS exists in two main crystalline forms, and this dualism is often a salient example of polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite.

Is zinc blende fcc or BCC?

Zincblende/sphalerite is based on a fcc lattice of anions whereas wurtzite is derived from an hcp array of anions. In both structures, the cations occupy one of the two types of tetrahedral holes present.

What is the difference between zinc blende and wurtzite structure?

What is the difference between zinc blende and wurtzite? Zinc blende and wurtzite are two forms of zinc sulfide. However, the key difference between zinc blende and wurtzite is that zinc blend is cubic, whereas wurtzite has a hexagonal structure.

What is the coordination number of wurtzite ZnS?

Coordination numbers of Zn2+ and S2− in the crystal structure of wurtzite are 4,4.

What is the difference in the structure of zinc blende and wurtzite?

What is arrangement of Zn2+ ions in wurtzite?

Coordination numbers of Zn2+ and S2− in the crystal structure of wurtzite are 4,4. Sulphide ions occupies ccp while zinc ions occupy alternate tetrahedral voids. Number of formula units per unit cell is 4.

What is difference between wurtzite and zinc blende?

What is the meaning of wurtzite?

Definition of wurtzite : a brownish black mineral ZnS that consists of zinc sulfide in hemimorphic hexagonal crystals or a fibrous state and that is polymorphous with sphalerite.

What is the formula of wurtzite?

Wurtzite is a zinc and iron sulfide mineral with the chemical formula (Zn,Fe)S, a less frequently encountered structural polymorph form of sphalerite.

What is the difference between zinc blende and wurtzite?

Is Wurtzite a metal?

Wurtzite is a zinc and iron sulfide mineral with the chemical formula (Zn,Fe)S, a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent….

Wurtzite
Category Sulfide mineral
Formula (repeating unit) (Zn,Fe)S
IMA symbol Wur
Strunz classification 2.CB.45

What is wurtzite used for?

Wurtzite Boron Nitride with plate shape particles is used as a raw material for sintering coarse grit polycrystalline structure powders, which are later used for manufacturing traditional cutting and grinding tools.

What is the structure of ZnS and Zn blende?

Zinc blende is the cubic crystals structure shown by zinc sulfide (ZnS). The structure has a diamond-like network. It is a thermodynamically more favoured structure than the other form of zinc sulfide. However, it can change its structure upon changing the temperature. For instance, zinc blende can become wurtzite if we change the temperature.

What is the difference between wurtzite and ZnS?

ZnS occurs in two common polytypes, zincblende (also called sphalerite) and wurtzite. The two types have these features in common: a 1:1 stoichiometry of Zn:S a coordination of 4 for each ion (4:4 coordination) tetrahedral coordination Zincblende/sphalerite is based on a fcc lattice of anions whereas wurtzite is derived from an hcp array of anions.

What is the difference between wurtzite and zincblende/sphalerite?

Zincblende/sphalerite is based on a fcc lattice of anions whereas wurtzite is derived from an hcp array of anions. In both structures, the cations occupy one of the two types of tetrahedral holes present. In either structure, the nearest neighbor connections are similar, but the distances and angles to further neighbors differs.

What is the Ionic and cationic radius of zinc blend?

The ionic radius for Zn 2+ is 74pm and for S 2- is 190pm. Therefore the ratio between cationic and anionic radii in zinc blend is 0.39 (74pm/190 pm) .This suggests a tetrahedral ion arrangement and four nearest neighbors from standard crystal structure prediction tables.